Obtaining and characterization of Mixed Oxides of 1-xSrxMnO3+-8

Authors

  • Carlos Vásquez Facultad de Ciencias, Universidad Nacional de Ingeniería, Lima - Perú
  • Silvia Ponce Facultad de Ciencias, Universidad Nacional de Ingeniería, Lima - Perú
  • Abel Gutarra Facultad de Ciencias, Universidad Nacional de Ingeniería, Lima - Perú

DOI:

https://doi.org/10.21754/tecnia.v11i2.525

Abstract

Mixed oxides of the La, Sr MnO, ± (x=0.0-0.5) series were prepared by the citrate method. The characterization was carried out structurally by X-ray diffraction (XRD) and elementally by inductive plasma coupling.
(ICP). The Mn/Mn" ratio of the oxide was determined by iodometry. The specific area of ​​the powder sample was
determined by BET. The electronic transport properties for different levels of La substitution were done at different temperatures between 300-700 K. The characterization results show us that our manufacturing technique produces oxides of the La, Sr MnOs type with favorable properties to be used as cathodes in fuel cells.

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References

[1] . EG&G Services Parsons, INC.. Fuel Cell Handbook (Fifth Edition), October 2000.

[2] . S. Tanasescu. N.D. Totir. D.I. Marchidan and A. Turcanu., Mater. Res. Bull 32, 915 (1997).

[3] . N.Q. Minh. J. Am. Ceram. Soc., 76 563 (1993).

[4] . T. Nitadori, T. Ichiki, and M. Misono; Bull. Chem. Soc. Jpn., 61 621 (1988).

[5] . A.J. Bosman and H. J. Van Daal, Advances in Physics, 19, N 77. I (1970).

[6] . D. Adler, and J. Feinleib, Physical Review B. 2, N 8. 3112 (1970).

[7] . V. N. Bogomolov. E. K. Kudinov, D.N. Mirlin. and Yu. A. Firsov, Soviet Physics-Solid State. 9. N 7, 1630 (1968).

[8] . Nevill Mott, Conduction in Non-Crystalline Materils, Claredon Press. Oxford, 55-69 (1987).

[9] . N. Tsuda. K. Kasu, A. Fujimori, and K Siratori. Electronic Conduction in Oxides.Springer. 181. 2000.

[10] .Gutarra, Electrochromism in titanium dioxide and titanium oxi-fluoride thin films. Ph. D. Thesis.

Facultad de Ciencias. UNI, Lima, Perú, (1998).

[11] .S. Ponce, Catalizadores del tipo Perovskita para la oxidación de CO y Gas Natural. Tesis Doctoral, Universidad Autónoma de Madrid, 1999.

[12] .L.G. Teguca, J.L.G. Fierro y J.M.D. Tascón. Adv. Catal, 36, 237. (1989).

[13] .D.L. Anderton y F.R. Sale. Powder Metall. 1(1979).

[14] .T. Nitadori. M. Muramatsu, and M. Misono: Bull.Chem. Soc. Jpn., 61 3831 (1988).

[15] .F. Huamán, W. Estrada, A. Gutarra, TECNIA. 8, N° 01, 77, Set. (1998).

[16] . Davydov. Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides, John Wiley & Sons, England, 1990, Chap. 1.

[17] .H.M. Zhang, Y. Teraoka, and N. Yamazoe, Chem. Lett.. 665 (1987).

[18] .JCPDS-Internacional Centre for Diffraction Data 47-0444 (1997).

[19] .S. Ponce, M. A. Peña. J.L.G. Fierro Applied Catalysis B: Enviromental 631, (1999).

[20] .D.Kuscer, M. Hrovat et.al. Mater Res. Bull., 35, 2525-2544, (2000).

Published

2001-12-01

How to Cite

[1]
C. Vásquez, S. Ponce, and A. Gutarra, “Obtaining and characterization of Mixed Oxides of 1-xSrxMnO3+-8”, TECNIA, vol. 11, no. 2, Dec. 2001.

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