Degradation of Volatile Organic Compounds and Pesticides by Heterogeneous Photocatalysis with Titanium Dioxide

Authors

  • Erika G. Tuesta Facultad de Ingeniería Química y Textil Universidad Nacional de Ingeniería, Lima - Perú
  • Yuri Zenitagoya Facultad de Ingeniería Química y Textil Universidad Nacional de Ingeniería, Lima - Perú
  • Silvia Ponce Facultad de Ingeniería Química y Textil Universidad Nacional de Ingeniería, Lima - Perú
  • Abel Gutarra Facultad de Ciencias, Universidad Nacional de Ingeniería, Lima - Perú

DOI:

https://doi.org/10.21754/tecnia.v12i1.506

Abstract

A new technology for photocatalytic degradation of organic pollutants was investigated. It is based on photocatalytical properties of TiO, nanoparticles, under UV radiation. Four aliphatic alcohols: methanol, ethanol, 2-propanol and 1-butanol, as well as a pesticide: cypermetrhin,
where irradiated on nanoparticles of TiO, photocatalist. A cylindrical photoreactor which use a medium pressure Hg lamp, as UV radiation source, was specially designed for this work. Our system was able to follow in situ degradation using a Fourier Transform Infrared Spectrometer (FT-IR) with a gas cell. From infrared spectra obtained a reaction mechanism was proposed. After few minutes of irradiation, complete mineralization were obtained, which indicates that photocatalytic method is an effective technique for degradation to this kind of pollutants.

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References

[1] . G. Kiely, Ingeniería Ambiental, Volumen Iy II, McGraw-Hill/Interamericana Editorial de España S.A., España, pág. 7-9,456-458,462-472, (1999).

[2] . M. Malato, J. Blanco, C. Estrada, E.Bandala,Eliminación de Contaminantes por Fotocatálisis Heterogénea, Red CYTED VIII-G,

pág. 269-284, (2001).

[3] . Memoria 98-99 Servicio Nacional de Sanidad Agraria (SENASA), Ministerio de Agricultura, Presidencia de la República, pág. 10-11, 41-45, (1998-1999).

[4] . A. Linsebigler, G. Lu, J. Yates, Chem. Rev., 95, 735-758, (1995).

[5] . A. Mills, S. Le Hunte, J. of Chemestry and Photobiology A: Chemestry, 108, 1-35, (1997).

[6] . J. Yu, L. Chan, P. Krause, J: Chem. Education, 75, Nº6, pág. 750-751, junio (1998).

[7] . J. Stark and J. Rabani, J. Phys. Chem. B, 103, 8524-8531, (1999).

[8] . Hussain Al-Ekabi and Nick Serpone, Lang- muir, 5, 250-255, (1989).

Published

2002-06-01

How to Cite

[1]
E. G. Tuesta, Y. Zenitagoya, S. Ponce, and A. Gutarra, “Degradation of Volatile Organic Compounds and Pesticides by Heterogeneous Photocatalysis with Titanium Dioxide”, TECNIA, vol. 12, no. 1, Jun. 2002.

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Articles