Prediction of phase equilibrium of the n-butylium acetate-cyclohexane system at low pressures
DOI:
https://doi.org/10.21754/tecnia.v15i1.453Keywords:
Liquid - vapor equilibrium, UNIFAC, boiling point, RefractometryAbstract
The group-contribution method of UNIFAC have been evaluated to predict phase equilibria for the n-butyl acetate-cyclohexane system at low pressures. The results show that this method predicts satisfactorily the studied system. The experimental results were obtained in a boiling point apparatus at low pressures, giving in this way experimental data from which we have scarce information.
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[1] Pilco Nuñez, A., Zavaleta Ortiz, J., "Aplicación de los métodos de contribuciónde grupos a la predicción del equilibrio de fases del sistema acetato de etilo-ciclohexano", Revista Tecnia, Vol. 14, Nº1, pp. 33- 39, 2004.
[2] Daubert T.E., Danner R.P., Sibul H.M., Stebbins C. C. "Physical and Thermodynamic Properties of Purc Chemicals". Data Compilation; Taylor & Francis: London, U.K., 1996.
[3] Smith, Van Ness, "Introducción a la Termodinámica en Ingeniería Química", McGraw Hill, 1989.
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