Prediction of natural gas densities using equations of state of Soave-Redlich-Kwong, Peng-Robinson and AGA8-DC92

Authors

  • Jack Zavaleta Ortiz Facultad de Ingeniería Química y Textil, Universidad Nacional de Ingeniería. Lima, Perú.
  • Alex Pilco Nuñez Facultad de Ingeniería Química y Textil, Universidad Nacional de Ingeniería. Lima, Perú.
  • Sergio Villanueva Guzmán Facultad de Ingeniería Química y Textil, Universidad Nacional de Ingeniería. Lima, Perú.

DOI:

https://doi.org/10.21754/tecnia.v16i2.389

Keywords:

natural gas, equation of state, compressibility factor, density

Abstract

In this work the Soave-Redlich-Kwong(SRK), Peng-Robinson (PR) y AGA8-DC92 (AGA) equations of state have been used to predict the density of different natural gas mixtures. AS a result, SRK and PR are strongly recommended for temperatures within the range 240-350 K. As for the pressure, SRK yielded better results within the range 1-8 MPa, whereas PR was more accurate for pressures ranging from 1 to 15 MPa. The errors obtained were smaller than 3% for all the 613 experimental point taken from the literature, which is convenient due to the fact that AGA is not easy to handle. Nevertheless, AGA displayed the best performance in every calculation and proved to be superior to either SRK or PR in the whole range of conditions used in this investigation. Finally, a computational tool has been developed to calculate density (ρ) and compressibility factor (Z). Such a tool incorporates an experimental database of ρ for different gas natural mixtures.

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References

[1] Starling K.E., Savidge J.L., "Compressibility Factors of Natural Gas and Other Related Hydrocarbon Gases", AGA Transmission Measurement Committee Report No. 8, 2nd edition, American Gas Association: Virginia, 1992.

[2] Jaeschke M., Humphreys A.E., "GERG Databank of High Accuracy Compressibility Factor Measurements", GERG Technical Monograph 4, Fortschritt-Berichte VDI Reihe 6. No. 251, 1991.

[3] Magee, J.M., Haynes, W.M., Hiza, M.J., "Isochoric (p,p,T) measurements for five natural gas mixtures from 7=(225 to 350) Kat pressures to 35MPa", J. Chem. Thermodynamics, 29, 1439-1454, 1997.

[4] Eapla L., Buryan P., Jedelský J., Rottner M., Linck J., "Isothermal pVT measurements on gas hydrocarbon mixtures using a vibrating- tube apparatus", J. Chem. Thermodynamics, 34, 657-667,2002.

[5] Biswas, S, N., S., Bominaar, S.A.R. C., Schouten J.A., Michels, J.P. J., Ten Seldam, C.A., "Compressibility Isotherms of Simulated Natural Gases", J. Chem. Eng. Data, 35, 35-38, 1990.

[6] Chamorro C.R., Segovia J.J., Martin M.C., Villamañan M.A., Estela-Uribe J.F., Trusler J.P.M., "Measurement of the (pressure, density, temperature) relation of two (methane + nitrogen) gas mixtures at temperatures between

and 400 K and pressures up to 20 MPa using an accurate single-sinker densimeter", J. Chem. Thermodynamics, 38, 916-922, 2006.

[7] Jingjun Z., Prashant P., Saquib E., Mert A., Holste J. C., Kenneth R. H., "(p.V.T) and phase equilibrium measurements for a natural gas-like mixture using an automated isochoric apparatus", J. Chem. Thermodynamics, 38, 1489-1494,2006.

[8] ISO 12213-2:2006, "Natural gas. Calculation of compression factor". Part 2: Calculation using molar-composition analysis.

[9] E. Poling, B., M. Prausnitz, J., O'Connell, J.P., "The Properties of Gas and Liquids", Fifth edition, McGraw-Hill, 2001.

[10] Smith J.M., Van Ness H.C., Abbott M.M., "Introducción a la Termodinámica en Ingeniería Química", Sexta edición en español, Editorial McGraw-Hill, Mexico, 2003.

Published

2006-12-01

How to Cite

[1]
J. Zavaleta Ortiz, A. Pilco Nuñez, and S. Villanueva Guzmán, “Prediction of natural gas densities using equations of state of Soave-Redlich-Kwong, Peng-Robinson and AGA8-DC92”, TECNIA, vol. 16, no. 2, pp. 25–31, Dec. 2006.

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